What is this thing? It was unscrewed so I screwed it on. What's it do? And is it sposed to be on or off? Been off since I got the truck, just figured I'd screw it on.
On most vehicles, that port would rarely or never be used. Normally, the cap would be removed only as necessary to leak-test the evap system by injecting smoke into it. The usual reason to suspect a leak is a CEL and corresponding trouble code.